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Polyaluminum chloride (PAC) - Determination of basicity

Abstract: 聚合氯化铝(PAC)的盐基度可以通过测定其氯离子含量来确定,常用的方法包括银氯滴定法、比色法和电位滴定法。在银氯滴定法中,PAC样品与银盐标准溶液反应生成沉淀,通过沉淀的重量或银离子含量计算盐基度。比色法涉及将PAC样品与铁铵盐反应,生成浅黄色络合物,通过比色计测定吸光度,并通过标准曲线计算氯离子含量。电位滴定法则使用氯离子选择性电极测定样品中的氯离子浓度以计算盐基度。在实验中,应根据实际情况选择合适的测定方法,并注意对样品进行适当的前处理,如调节pH值或添加指示剂,以确保结果的准确性。

The basicity of polyaluminum chloride (PAC) can be determined by measuring its chloride ion content. Commonly used measurement methods include the following:

  1. Silver-chloride titration method: react the PAC sample with the silver salt standard solution, so that the chloride ions in the PAC react with the silver ions to form a precipitate, and calculate the basicity of the PAC by the weight of the precipitate or the dissolved silver ion content.

  2. Colorimetric method: react the PAC sample with iron ammonium salt to form a light yellow complex, measure the absorbance of the complex with a Colorimeter, calculate the chloride ion content in PAC according to the standard curve, and then calculate the salt of PAC basis.

  3. Potentiometric titration method: After dissolving the PAC sample, measure the chloride ion concentration with a chloride ion selective electrode to calculate the basicity of PAC.

NBCHAO reminds you: Different determination methods may carry out different pretreatments on PAC samples, such as adjusting pH value, adding indicators, etc. When conducting experiments, the appropriate measurement method should be selected according to the actual situation.

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