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Difference between surface tension and contact angle

Abstract: 表面张力和接触角都是描述液体与固体接触性质的物理量,但它们的定义和应用有所不同。表面张力指液体表面分子间的相互作用力,使液体表面形成稳定的界面,其单位为牛顿/米(N/m)。它影响液滴的形状和稳定性。接触角则是液体在固体表面上的接触线与固体表面之间的夹角,用来描述液体的湿润性,其单位为度(°)。接触角越小,液体在固体表面上的湿润性越好。表面张力和接触角的测量方法也不同,前者可以通过悬滴法、平衡法等测量,而后者则常用自动接触角仪或手动测量仪器。在实际应用中,表面张力常用于液滴和泡沫的稳定性研究,而接触角用于评价材料的亲水性或疏水性。

Surface tension and contact angle are both physical quantities that describe the properties of a liquid on a solid surface, but there are some differences between them.

The difference between surface tension and contact angle with Figure 1

Surface tension refers to the interaction force between molecules on the surface of a liquid. These forces enable the molecules on the surface to form a tightly bound layer on the surface, so that the surface of the liquid forms a relatively stable interface. The amount of surface tension determines whether a liquid surface can form a concave shape, and also determines whether droplets can maintain their shape on the surface without being merged or broken up. Surface tension is usually measured in Newtons per meter (N/m).

The contact angle is the angle between the contact line between the liquid and the solid and the solid surface, which can be used to describe the wettability of the liquid on the solid surface. The smaller the contact angle, the better the wettability of the liquid on the solid surface, and the ability of the droplet to spread on the surface. And when the contact angle is greater than 90 degrees, the liquid cannot spread on the solid surface, forming a water drop shape. Therefore, the contact angle can be used to evaluate the hydrophilicity or hydrophobicity of the coating surface. Contact angle is measured in degrees (°).

In addition, the application and measurement methods of surface tension and contact angle vary.

Surface tension can be used in the formation and stabilization of droplets and foams, wettability of liquids, and separation techniques. The contact angle can be used to evaluate the hydrophilicity or hydrophobicity of the material surface, the wettability of coatings and inks, as well as surface cleaning and surface modification.

The measurement of surface tension can be carried out by methods such as pendant drop method, balance method, reflux method, etc., and the measurement of contact angle can be carried out by automatic contact angle meter or manual measuring instrument. In practical applications, these measurement methods need to select appropriate methods according to the needs of specific application fields.

In short, both surface tension and contact angle are physical quantities that describe the properties of a liquid on a solid surface, but surface tension describes the interaction force between molecules on the liquid surface, and contact angle describes the angle between the contact line between the liquid and the solid and the solid surface. Their properties and applications vary, but they are widely used and studied in industry and science.

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