Back
Knowledge

The skinning property and its control method in oxidation drying varnishes and Paints

Abstract: 本文探讨了氧化干燥型清漆和色漆中的结皮性及其控制方法。结皮性指的是涂料在储存或使用过程中形成的干燥薄膜,这一现象可能导致涂料质量下降、施工效果受损。结皮性的重要性体现在它不仅影响涂料的成膜性能,还可能引发凝胶和变质等问题,从而增加生产成本。文章介绍了两种主要的结皮性测定方法:密闭试验和敞罐试验。密闭试验通过在密闭环境下存储涂料并检查结皮情况,而敞罐试验则观察涂料在开盖状态下的结皮速度。控制结皮性的方法包括使用抗结皮添加剂、优化储存条件、定期检查和测试,以及采用稳定的生产工艺。这些措施有助于减少结皮现象,确保涂料质量,提高施工效果。

Coating is an important material widely used in construction, industry and home decoration. The problem of skinning has always been a serious challenge during the production and storage of Coating. Skinning refers to the drying film formed on the surface of Coating. It appears when it is uncomfortable during storage or use, which may cause the Coating mass to decrease and affect the construction effect. This article will discuss the skinning properties and control methods in oxidation drying varnishes and Paints.

The importance of skinning

The skinning tendency of oxidation drying varnishes and Paints in storage is a key test item for storage stability. Skinning is not only an Appearance problem, but more importantly, it will affect the composition and color base ratio of Coating, thereby directly affecting the film formation performance of Coating. In addition, skinning may also lead to Miscellaneous problems in Coating, such as gel, deterioration, etc., which further reduces the mass of Coating, which may lead to a decrease in construction mass and increase production costs.

Determination method of skinning

The measurement of skinning usually involves two aspects: one is to measure the skinning possibility of Coating under closed conditions, and the other is to measure the skinning speed under open cover conditions.

Closure test

The airtight test is usually carried out using a 125mL wide-mouth grinded glass bottle or a 0.33L lacquer can. The sample is loaded into a bottle or lacquer can, the volume is about 95mL, and the sample in the lacquer can should be 15mm away from the top of the can. Afterwards, store it in the dark at 23 ℃ ± 2 ℃ for 48 hours, and then open the bottle or can cap to check for skinning. If no skinning is observed for three consecutive 48-hour periods, it can be confirmed that the Coating is not skinning. Alternatively, the lacquer can can be stored in the natural environment at room temperature for one year in the dark, and then checked for skinning to more fully assess skinning.

Open tank test

The open tank test is a more on-the-spot test method in which the specimen is loaded into a paint can to half the depth of the paint can and the lid is kept open. During the test, it is necessary to observe from time to time until skinning is observed. To better assess skinning, it is best to test with samples of known properties at the same time and compare the skinning of the two at different stages.

Methods of controlling skinning

To control skinning in oxidation drying varnishes and Paints, the following measures can be taken:

Use anti-skinning additives

Adding anti-skinning additives to the formulation of Coating can effectively reduce the occurrence of skinning. These additives can interfere with the chemical reactions in which skinning is formed, thereby delaying or preventing the formation of skinning.

Optimize storage conditions

Closed storage and protection from light are important factors in reducing skinning. Ensuring that storage containers are sealed and protected from light, avoiding direct sunlight and high temperature environments, can reduce the risk of skinning.

Regular inspection and testing

Regular closed test and open tank test of Coating can detect skinning problems in time and take measures to repair or improve the formula.

Adopt a stable production process

During the production process, controlling factors such as the pH value of the Coating, solvent selection and additive usage can help reduce the risk of skinning.


Skinning is an important mass problem in oxidation drying varnishes and Paints, which will affect the stability and construction effect of Coating. Through appropriate test methods and control measures, the occurrence of skinning can be reduced or prevented. This is essential to ensure Coating mass and improve construction effect, and needs to be paid attention to during Coating production and storage. Through continuous research and practice, we can continuously improve Coating formulations and production processes to meet the challenges posed by skinning and provide more possibilities for the development of the Coating industry.