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RCA paper tape testing wear resistance of polyurethane coating for silicone rubber buttons

Author: 朱鹏,刘桃凤,吴绥菊,马海燕
Source: 《硅橡胶按键用聚氨酯涂层的性能研究》
Abstract: 这篇文章研究了RCA纸带测试在硅橡胶按键上应用的聚氨酯涂层的耐磨性。由于硅橡胶的耐磨性较差,通常会在其表面喷涂保护涂层以提高耐磨性能。本文考察了聚氨酯(PU)化学结构对涂层耐乙醇性能的影响,并通过优化消光粉等助剂提高了PU涂层的耐磨性和耐乙醇性。传统的RCA测试方法不足以模拟实际使用情况,因此本文引入了在乙醇中浸泡1小时后的耐磨性测试。结果表明,改进后的PU涂层在耐乙醇RCA测试中的表现优于传统PU涂层,符合客户对硅胶按键保护涂层的高要求。这一改进提高了涂层的耐磨性和耐乙醇性能,满足了国外客户的使用标准。

Compared with ordinary rubber, silicone rubber has both high bond energy and high flexibility, and has excellent heat resistance, aging resistance, low compression and long-term deformation and other unique comprehensive properties and electrical properties. It is widely used in aerospace, aviation, electronic appliances It is widely used in industry and other fields, and its demand is also growing .

The silicone rubber used as a mobile phone, remote control button, and sheath itself has poor wear resistance. Therefore, the surface is often sprayed with a protective coating to increase its wear resistance. Zhang Wei and others used polyurethane prepolymer to modify epoxy resin , and modified epoxy with rigid inorganic fillers, which can improve the acid resistance and abrasion resistance of coatings to varying degrees. Usually, the customer's requirements for the tape abrasion resistance (RCA) of the PU protective coating of the silicone keypad generally range from 500 to 800 cycles . Key protection coatings place higher demands. Compared with the traditional test method, it proposes a test method for ethanol resistance and friction resistance. After 1 hour of ethanol resistance, the RCA test requires more than 400 cycles.

For this reason, this paper mainly investigates the influence of PU chemical structure on the ethanol resistance of the coating , combined with the optimization of matting powder and other additives to further improve the ethanol resistance and friction resistance of the PU coating, so as to improve the service life and meet the needs of foreign customers. Requirements.

Determination of coating wear resistance

Silicone rubber buttons, mobile phone sheaths, etc. are often in contact with hands, and are prone to be stained with sweat. Touching will cause the coating to wear out. Today's commonly used coating wear resistance measurement is not enough to simulate the actual working conditions. For this reason, the new test method of wear resistance requires that before the measurement, the key is immersed in ethanol for 1 hour to measure the wear resistance of the coating.

rca paper tape testing the abrasion resistance of polyurethane coatings for silicone rubber keys with Figure 1

Coating wear resistance

For this reason, this paper selects a typical commercial product PU-1 coating (the number of wear-resisting circles is 1500 circles when not soaked in ethanol ) and the PU-2 coating selected in this paper after adding other additives and ethanol-resistant resin and matting powder. , and the results are shown in the table.

It can be seen that there is no obvious difference in performance between PU-1 and PU-2 in the ordinary RCA test ; while PU-2 has better ethanol resistance than PU-1, so its ethanol resistance RCA test is more excellent, which meets the customer's requirements.

in conclusion

Compared with the existing PU wear-resistant coating, the improved PU coating has improved ethanol resistance, showing better     , meeting customer requirements.


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