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Preparation and Performance Test of Ultraviolet Curable Urushiol-Based Epoxy Acrylate Coatings

Author: 路正鸿
Source: 西北农林科技大学
Abstract: 本文介绍了紫外光固化漆酚基环氧丙烯酸酯涂层的制备及性能测试。首先,使用无水乙醇清洁马口铁片和载玻片,然后在马口铁片上均匀涂覆漆酚基环氧丙烯酸酯涂层,并用2000W紫外光固化剂固化一定时间,之后放入干燥箱中干燥6小时以备测试。测试包括漆膜的力学性能、光泽度、固含量和耐腐蚀性。力学性能测试遵循GB/T 1731-93、GB/T 6379-1996、GB/T 9286-1998和GB/T 1732-1993标准,光泽度测试遵循GB/T 1743-1979标准。固含量测试通过丙酮萃取测量未萃取样品的质量变化。耐腐蚀性测试通过浸泡实验观察涂层的表面状态。

Wipe the tinplate sheet and glass slide with absolute ethanol to remove impurities on the surface for later use. Apply the pre- prepared urushiol-based epoxy acrylate to the tinplate so that the coating meets the paint film thickness standard. The coating needs to be uniform, otherwise there will be differences in performance. Place the painted film under 2000W UV curing agent, cure for a certain period of time, take it out and put it in the Drying Oven for 6 hours, and prepare for testing various properties. Figure 3-1 is the flow chart of coating preparation.

Preparation and performance test of UV-cured urushiol-based epoxy acrylate coating Figure 1

Performance Testing

Mechanical properties of UV-cured film

This test tests the mechanical properties of the cured film: follow the national standard GB/T 1731-93 to test the flexibility of the paint film , follow the national standard GB/T6379-1996 to test the hardness, follow the national standard GB/T 9286-1998 to test the paint The hardness of the film has passed the national standard GB/T1732-1993 to test the impact resistance of the paint film.

Gloss of UV-cured film

This test uses a gloss meter to test the gloss of the paint film, and follows the national standard GB/T1743-1979 to test the gloss of the paint film.

Solid content of UV curable film

In this test, acetone solution was used for extraction first, and the mass of the remaining insoluble matter in the reaction system can be determined by the degree of . The cured product contains unsaturated double bond resin, forming a three-dimensional network structure. Calculated as follows:

Preparation and performance test of UV-cured urushiol-based epoxy acrylate coating Figure 2

In the formula: m1 is the unextracted mass of the sample:  m2 is the mass of the sample after extraction;

Note: The extracted tinplate sheet should be washed and dried before the quality can be tested.

Corrosion Resistance Test

In this experiment, according to the national standard GB 9274-88 method, the UV cured film was soaked in the test. After soaking in the solution for a while, the surface state of the coating was observed.


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