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Customized pH electrode structure, function and type [Common sense]

Abstract: 本文详细介绍了定制pH电极的结构、功能及类型。pH电极主要由玻璃膜、液络部、参比系统和参比电解液组成。玻璃膜作为核心技术,感应溶液中H+的活度,其质量受膜类型和形状影响。液络部连接参比系统与样品溶液,定制电极的参比系统包括长寿命参比系统和银离子捕捉阱,确保长期稳定性和防止堵塞。特殊参比电解液,如固体聚合物和Protelyte,适用于不同样品类型,满足各类测量需求。

The structure of the pH electrode includes glass membrane, junction, internal solution, reference system and reference electrolyte etc. The manufacture and assembly of each part of the customized pH electrode is the fusion of professional technology and craftsmanship.

Customized pH electrode structure, function and type [common knowledge] with picture 1

glass film

The glass membrane is a sensitive membrane for the pH electrode to react to the H+ activity of the solution. The quality of the glass membrane depends on type and shape of the membrane, which is the core technology of the pH electrode.

Customized pH electrode structure, function and type [common knowledge] with picture 2


Customized pH electrode structure, function and type [common knowledge] with picture 3

The shape of the glass membrane

Customized pH electrode structure, function and type [common knowledge] with picture 4

Junction

The junction is the connection interface between the reference system and the sample solution, and the custom electrode adopts the junction of the following structure.

Customized pH electrode structure, function and type [common knowledge] with picture 5

reference system

●Long-life reference system—consists of a thin glass tube, silver chloride particles and silver wire. The head of the thin glass tube is stuffed with cotton. This structure contains sufficient silver chloride particles, which can further ensure the long-term stability of the reference electrode. , The reference electrolyte used with the long-life reference system does not contain silver ions, which prevents the reaction with the sulfide and protein in the sample to produce precipitation and block the junction.

Customized pH electrode structure, function and type [General Knowledge] with Figure 6

Silver ion trap reference system - the silver ion trap reference system is a combination of "long-life reference system" and "silver ion trap". There is no Ag+ in the electrolyte, so as to avoid the blockage of the junction caused by samples containing sulfide and protein or TRIS buffer.

Customized pH electrode structure, function and type [common knowledge] with Figure 7

reference electrolyte

In addition to the routinely used 3M KCl solution and gel, this custom electrode also uses the following special reference electrolytes:

  • Solid polymer reference electrolyte - using an open junction, the polymer is in direct contact with the sample, and the pressure is 6 bar, which is suitable for almost all measurement fields, including oily samples, low ion samples, protein samples and suspended matter samples.

  • Protelyte reference electrolyte - suitable for protein samples, low temperature samples and viscous samples.

  • Pre-pressurized reference electrolyte - a pressurized system is set in the gel electrolyte to ensure that the electrolyte can continue to seep out even in viscous samples.

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