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Which performance subjects should be tested for phenolic resin used in phenolic molding compounds? How to judge the results?

Abstract: 本文介绍了酚醛模塑料用酚醛树脂的性能检测要求,依据GB/T 30772—2014标准。酚醛树脂分为固体和液体两类,且根据不同改性类型有六种分类。固体酚醛树脂的检测项目包括外观(无色至棕色,视代号而定)、聚合时间、游离苯酚含量、游动度、软化点、溶解黏度、pH值和水分含量。液体酚醛树脂的要求则包括外观、固含量、游离苯酚和甲醛含量、水分及pH值。这些检测标准确保了酚醛树脂在模塑料应用中的质量和性能。

Phenolic resins for phenolic molding compounds are synthesized from phenols and aldehydes as main raw materials. According to the state of the product, it is divided into two types: solid and liquid, which are represented by S and L respectively. Divided into six categories according to product properties: pure resin (code 1), cardanol modified resin (code 2), melamine modified resin (code 3), polyvinyl butyral (PVB) modified resin (code 4) , Aniline modified resin (code 5), other modified resins (code 6).

Today I will introduce what conditions should be met in the performance testing of phenolic resins for phenolic molding compounds under the provisions of GB/T30772-2014. The product needs to be named before testing to prevent confusion. See below.

What performance subjects should be tested for phenolic resins for phenolic molding compounds?  How to judge the results?  Picture 1

Item detection

Performance requirements of solid phenolic resin for phenolic molding

1. Appearance: Codes 1, 3, and 4 should be in the form of colorless to yellow solids without obvious impurities; code 2 should be in the form of brown solids without obvious impurities; code 5 should be in the form of light yellow to brown solids without obvious impurities Visible impurities;

2. The polymerization time is 20s~11s.

3. Free phenol content ≤ 5.0%.

4. The swimming degree is 13mm~80mm.

5. The softening point is 85℃~125℃.

6. The solution viscosity is 45MPa*s~300MPa*s.

7. The pH value is 3.0~6.5.

8. Moisture content ≤1.0%.

What performance subjects should be tested for phenolic resins for phenolic molding compounds?  How to judge the results?  Picture 2

Performance requirements of liquid phenolic resins for phenolic molding compounds

 Code 6: The appearance should be brown-red/brown-yellow translucent liquid, without obvious visible impurities; moisture ≤ 10.0%; solid content ≥ 40.0%; free phenol content ≤ 15.0%; free formaldehyde content ≤ 2.0%; pH value 7.0 ~9.0.What performance subjects should be tested for phenolic resins for phenolic molding compounds?  How to judge the results?  Picture 3

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