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How do temperature and solvents affect viscosity?

Abstract: 本文探讨了温度和溶剂对粘度的影响。温度对粘度有显著影响,通常需要在相同温度下(如23°C)测量粘度,以确保准确性。温度每变化一度通常会导致粘度的恒定变化,涂层的粘度可以通过加热降低,这在涂层应用中很常见,例如在紫外线固化涂料中。溶剂的添加也会显著影响粘度,较高的树脂固体会增加溶液的粘度,而溶剂则会降低它。不同的溶剂(如真溶剂、潜溶剂或非溶剂)会导致不同程度的粘度变化,尤其在溶解树脂时效果更加明显。

temperature effect

Viscosity is greatly affected by temperature. Measurements should be performed at the same temperature (typically 23°C). A viscosity value without a temperature symbol is incomplete. Although each liquid is affected differently by temperature changes, the change in temperature per degree is usually a constant for a given material. The issue of temperature effects has been adequately discussed elsewhere. It can be said that the viscosity of the coating can be reduced by heating, and this principle is used in many coating application systems. Reducing viscosity by heating can also be used after the material has been applied. Preheating UV-cured coatings prior to UV exposure is often beneficial in leveling these sometimes sticky materials.

solvent effect

Higher resin solids yielded higher solution viscosity, while addition of solvent decreased viscosity. It is worth noting that viscosity changes are much more pronounced in the case of soluble resins (polymers) than in the case of insoluble pigments or plastic particles. For example, while a coating may be highly viscous at 50% solids, a plastisol suspension (plastic particles in a liquid plasticizer) may be moderately viscous at 80% solids. Different solvents produce different degrees of viscosity reduction, depending on whether they are true solvents, latent solvents, or non-solvents.

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