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What is yield stress? measurement principle

Abstract: 本文讨论了屈服应力的定义和测量原理。屈服应力是指流体开始流动所需的最小剪切应力,也称为“宾汉应力”。这类材料通常被称为“宾汉塑性”或粘塑性。虽然屈服应力的定义简单,但其测量较为复杂,主要通过剪切蠕变实验在应力控制流变仪中完成。此实验可施加1至5达因/cm²的应力范围,适用于大多数固体含量低的涂料。另一种测量方法是通过应力与粘度的恒定应变率测量来估计屈服应力,或使用阶跃应变后的应力松弛测量来得到屈服应力的估计值。这些方法对于理解和分析涂层现象中的屈服应力具有重要意义。

In the case of fluids, yield stress is defined as the minimum shear stress required to initiate flow. It is also often referred to as "Bingham stress", and materials exhibiting yield stress are often referred to as "Bingham plasticity" or viscoplasticity. While easy to define, this quantity is not so easy to measure. However, its importance in coating phenomena is widely accepted.

The most direct way to measure this stress is through shear creep experiments. This can be done in so-called stress-controlled rheometers. The minimum stress that can be exerted on a sample varies by instrument type, but through judicious use of geometry, stresses (shear forces) in the range of 1 to 5 dynes/cm2 can be applied. This is the range of yield stress exhibited by most low solids coatings. However, traffic detection is not simple. In the traditional sense, when flow occurs, the strain measured in the sample needs to be linear in time. This may require long measurements.

Estimates of yield stress can be obtained from constant strain rate measurements of stress and viscosity. When viscosity is plotted against stress, its magnitude appears to approach infinity at low stress. The asymptote on the stress axis gives an estimate of the yield stress.

Another method used is the stress relaxation measurement after applying a step strain. For materials exhibiting viscoplasticity, the stress decays to a nonzero value as an estimate of the yield stress.

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