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What are surface tension, contact angle, hydrophilic and hydrophobic surfaces?

Abstract: 本文探讨了表面张力、接触角以及亲水和疏水表面的概念。表面张力是液体的一种特性,源于表面分子之间的不平衡内聚力,使液体表面表现出类似弹性膜的特性,极性液体通常具有较高的表面张力。接触角是指液体在固体表面上,液体、固体和气体相交处的角度。亲水表面与水的接触角小于90°,而疏水表面则大于90°。这些特性对液体与固体的相互作用及材料的应用具有重要影响。

Surface Tension

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 1

Surface tension is a property of liquids caused by unbalanced molecular cohesion at or near the surface, with the result that the surface tends to shrink and behave like a stretched elastic film. Polar liquids exhibit strong surface tension.

Surface tension of various air-liquid interfaces at 293 K (West, RC (Ed.)

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 2

Variation of surface tension at the air-water interface with temperature (West, RC (Ed.).

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 3

Contact angle

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 4

The equilibrium contact angle of a liquid on a rigid surface, measured at the contact line where the three phases (liquid, solid, gas) within the liquid meet.

For example, a water bead on glass has a zero contact angle, but a water bead on an oily surface or plastic may have a contact angle of 90° or greater.

Hydrophilic and Hydrophobic Surfaces

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 5

A substrate surface is said to be hydrophobic when the contact angle with water is greater than 90°. Example Figure A above.

When the contact angle with water is less than 90°, the substrate surface is said to be hydrophilic. Example Figure B above.

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