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Two defects of paint film adhesion - saponification and undercutting

Abstract: 本文探讨了漆膜附着力的两种主要缺陷:皂化和咬底。皂化发生在油性漆、醇酸树脂漆、酚醛树脂漆或环氧树脂漆直接涂覆在镀锌表面时,与锌反应导致涂料剥落。为避免此问题,建议在镀锌表面涂磷化底漆或使用环氧磷酸锌涂料。此外,这些涂料也不应直接涂在富锌涂料表面,而应采用乙烯基涂料或高性能环氧、聚氨酯涂料。咬底则发生在强溶剂涂料涂覆在已氧化干燥的涂层表面时,强溶剂可能会破坏旧涂层,导致附着力丧失。为避免咬底,应了解原涂装体系并在实际涂装前进行小面积试验。咬底问题还可能因表面有蜡、前涂层干燥不足或涂层附着力不足等原因引起。

saponification

Oil-based paint, alkyd resin paint, phenolic resin paint, and epoxy resin paint cannot be directly painted on the galvanized surface, otherwise it is easy to have a saponification reaction with zinc, resulting in peeling off of the paint. Therefore, phosphating primers are usually applied on the surface of galvanized parts, or epoxy zinc phosphate coatings are used to ensure the adhesion of subsequent coatings. Likewise, these coatings cannot be applied directly to zinc-rich painted surfaces. Epoxy zinc-rich paint or inorganic zinc-rich paint surfaces are usually coated with vinyl coatings or high-performance epoxy and polyurethane coatings.

Two defects of paint film adhesion - saponification and bottom bite with picture 1

Bite the bottom

Undercoating occurs mainly when coatings containing strong solvents are applied to the surface of oxidatively dried coatings. Strong solvents will bite off the previous coat, and over time the adhesion between the coat and the substrate will be lost. Such as epoxy coatings, chlorinated rubber coatings, polyurethane coatings, etc., are prone to bottoming when applied on the surface of alkyd coatings. Pay particular attention to this problem when refinishing and painting old coatings. First understand the previous coating system. In actual painting, a small area test can be carried out to observe the effect. Other causes could be wax on the surface, insufficient drying of the previous coat, or insufficient adhesion between coats.

Two defects of paint film adhesion - saponification and bottoming picture 2

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